张夏

姓   名

张夏

性    别

男

出    生

年    月

1989.02

政治面貌

中共党员

学历

博士

毕业时间

2018.06

专业

工业催化

办公地址

山东省济南市长清区齐鲁工业大学国重实验室北楼B527

邮箱

zx21619

@163.com

办公电话

15802269737 

个人简历：

2007-2011 湖南科技大学化学院 化学专业 学士

2011-2014 济南大学化学与化工学院 无机化学专业 硕士

2014-2018 天津大学化工学院 精细化工专业 博士

2018年6月-2018年9月 山东第一医科大学药物研究所 助理研究员

2018年9月-至今 齐鲁工业大学前沿交叉学科研究院 讲师

研究方向：

（1）有机场效应晶体管器件的制备和性能研究：大环共轭配合物作为有机半导体材料在有机场效应晶体管中的应用；（2）酶-电催化产氢系统研究：金属酶仿生催化体系构建、仿生氢化酶模型化合物的合成及产氢性能研究；（3）精细化学品的绿色催化合成与光催化材料的制备与应用

科研项目：

1.[NiFe]-氢化酶功能导向的仿生催化体系研究，山东省自然科学基金（ZR2020QB042）主持

2.木质纤维素纳米复合材料制备及性质研究，绿色造纸国家重点实验室自主研究基金（ZZ20200129）主持

3.2021 年基础研究加强培育计划研究项目，齐鲁工业大学国家青年基金培育项目（020560036）   主持

4.[Fe]-及[FeFe]-氢化酶仿生催化剂的合成和性质研究，齐鲁工业大学培新基金（2023PX079） 主持

5.基于知识产权共享的产学研融合创新机制研究（2025QB32），山东科技情报学会2025年度研究课题，主持

6细菌纤维素多尺度结构调控及防油防水机制，山东省自然科学基金（ZR2020QB042）参与

7.基于贵金属替代的氢分子氧化仿生催化剂制备及应用，天津市自然科学基金(16JCYBJC20800) 参与

8.[Fe]-氢化酶功能导向的仿生电催化产氢体系研究   国家自然科学基金 (21103121)  参与

9.酞菁基场效应晶体管阵列的构筑及化学传感性质研究，国家自然科学基金 (21371073)  参与

10.微环境调控下芳烃选择性氧化制备苯酚的仿生催化体系研究 国家自然科学基金 (21276187)  参与

11. Ru/Pt共改性梯度MCrAlY涂层的制备及性能研究 齐鲁工业大学培英基金（2022PY063）参与

代表性论文：

(1) Zhang Xia, Sun Jiazhen, Gao Meixiang. A Novel N-heterocyclic Carbene Containing [Fe-Fe] Hydrogenase Model Complex as Bio-Mimetic Catalyst for Proton Reduction and Benzene Hydroxylation [J]. Catalysis Letters, 2025, 29: 155-159.

(2) 尹龙, 张夏. 一种双铁氢化酶配合物(μ-dmedt)Fe₂(CO)₅[Tricyclohexyl phosphine]的制备及其羟基化苯酚的性能的探究 [J]. 山东化工, 2023, 52(8): 1-4.

(3)张夏. 一种单齿膦螯合的铁铁双核氢化酶模型物及其制备方法与应用 [P]. 中国专利: 2023115446989, 2023.

(4) Gao Meixiang,  Lu Meng,  Zhang Xia,  Luo Zhenhui, Xiao Jiaqi. Application of fiber biochar–MOF matrix composites in electrochemical energy storage [J]. Polymers, 2022, 14(12): 2419.

(5) Ma Xiaoyuan, Zhang Xia, Wang Jingchao, Li Siyi, Zhang Tianyong, Jiang Shuang, Li Bin, Diphosphine ligandcontaining model complex of [Fe]H2ase active site as direct phenol hydroxylation catalyst in the aqueous phase. Journal of Chemical Technology & Biotechnology, 2022, 97, 1200-1206.

(6) Zhang Xia, Gao Meixiang, Xiao Jiaqi. A sandwich mixed (Phthalocyaninato) (Porphyrinato) Europium triple-decker: Balanced-mobility, ambipolar organic thin-film transistor [J]. Materials Today Communications, 2021, 29: 103003.

(7) Yan Fei, Li Ping, Zhang Xia. CO and C₃H₆ oxidation over La0.9Sr0.1CoO3 catalysts: Influence of preparation solvent [J]. Korean Journal of Chemical Engineering, 2021, 38(5): 945-951.

(8) 张夏, 肖加奇. 一种氮杂环卡宾基-[Fe-Fe]氢化酶模型化合物及其制备方法与应用 [P]. 中国专利: 2021106008986, 2021.

(9) Zhang Xia, Liu Lihong, Xiao Jiaqi, et al. Organic(TPyP)Eu2[Pc(OPh)8]2/CdS Self-assembled Hybrid Nano-Transistors with High Ambipolar Performance [J]. Journal of Materials Research and Technology, 2020, 9(6): 13682-13691.

(10) Zhang Xia, Liu Lihong, Cao Weiming, et al. Di-Iron Analogue of [FeFe]-Hydrogenase Active Site as a Molecular Electro-catalyst for Proton Reduction [J]. Catalysis Letters, 2020, 150: 3409-3414.

(11) Zhang Xia, Liu Lihong, Li Yingzhou. Synthesis and Benzene Hydroxylation Properties of Amino Substituted [FeFe] Hydrogenase Model Compounds [J]. Catalysis Letters, 2020, 150: 2879-2885.

(12) Lv Dongjun, Sung Hsiu-Sun,  Li Xiujing,  Zhang Xia,  Li Zheng,  Chen Dufang.  Effects of single layer graphene and graphene oxide modification on the properties of phthalocyanine blue pigments [J]. Dyes and Pigments, 2020, 180: 108449.

(13) 张夏, 肖加奇. 双齿膦[2Fe2S]二铁络合物及其制备方法与应用 [P]. 中国专利: 2020101343466, 2020.

(14) GaoFeng,  Zhang Xia,  Wang Tengfei, Xiao Jiaqi . Quinolone hybrids and their anti-cancer activities: An overview [J]. European Journal of Medicinal Chemistry, 2019, 165: 59-79.

(15) Gao Feng, Wang Tengfei, Gao Meixiang, Zhang Xia, Liu Zhuqing, Zhao ShiJia, Lv ZaoSheng, Xiao Jiaqi.  Benzofuran-isatin-imine hybrids tethered via different length alkyl linkers: Design, synthesis and in vitro evaluation of anti-tubercular and anti-bacterial activities as well as cytotoxicity [J]. European Journal of Medicinal Chemistry, 2019, 165: 323-331.

(16) Zhang Xia, Ma Xiaoyuan, Zhang Tianyong, et al. The influence of phosphine ligand Substituted [2Fe2S] model complexes as electro-catalyst on proton reduction [J]. RSC Advances, 2018, 8: 42262-42268.

(17)Zhang Xia, Zhang Tianyong, Li Yiwen, et al. Catalytic property of [FeFe]-hydrogenase model complex: (μ-dmedt)Fe2(CO)5 for the selective phenol hydroxylation [J]. Catalysis Today, 2018, 8: 42262-42268.

(18) Zhang Guanghui, Zhang Tianyong, Li Bin, Jiang Shuang, Zhang Xia, et al. Tubular structure TiO₂/C/TiO₂ hybrid derived from the waste of the fluff of chinar tree [J]. Journal of Alloys & Compounds, 2018, 737: 774-789.

(19) Zhang Guanghui, Zhang Tianyong, Li Bin, Jiang Shuang, Zhang Xia, et al. An ingenious strategy of preparing TiO₂/gC₃N₄ heterojunction photocatalyst [J]. Applied Surface Science, 2018, 433: 963-974.

(20) Zhang Xia, Zhang Tianyong, Li Bin, et al. Synthesis and electrochemical properties of [FeFe]-hydrogenase model complexes with acid-functionalized or base-functionalized ligands [J]. Journal of Applied Electrochemistry, 2017, 5: 583-591.

(21) Zhang Xia, Zhang Tianyong, Li Bin, et al. Effect of the terminal ligands of [FeFe]-hydrogenase model complexes on proton reduction properties and catalytic hydroxylation of benzene [J]. ChemistrySelect, 2017, 2: 3306-3310.

(22) Zhang Xia, Zhang Tianyong, Li Yiwen, et al. Bio-inspired Catalyst: [(μ-(SCH(CH₂CH₃)CH₂S))Fe(CO)₅]₂(m,k1,k1-DPPF) for Proton Reduction and Phenol Hydroxylation [J]. ChemistrySelect, 2017, 29: 9407-9411.

(23) Zhang Xia, Zhang Tianyong, Li Bin, et al. Direct synthesis of phenol by novel [FeFe]-hydrogenase model complexes as catalysts of benzene hydroxylation with H₂O₂ [J]. RSC Advances, 2017, 7: 2934-2942.

(24) Hai Li, Zhang Tianyong, Zhang Xia, et al. Reversible isomerization of a novel [FeFe]-hydrogenase model complex and water-promoted electrocatalytic proton reduction [J]. Electrochemistry Communications, 2017, 82: 66-70.

(25) Hai Li, Zhang Tianyong, Zhang Xia, et al. Catalytic hydroxylation of phenol to dihydroxybenzene by Fe(II) complex in aqueous phase at ambient temperature [J]. Catalysis Communications, 2017, 101: 93-97.

(26) Hai Li, Zhang Tianyong, Li Bin, Jiang Shuang, Zhang Xia, et al. Design and Performance of Catalysts for Direct Hydroxylation of Phenol to Dihydroxybenzene [J]. Progress in Chemistry (化学进展), 2017, 29: 785-795.

(27) Li Bin, Wu Wubin, Zhang Tianyong, Jiang Shuang, Zhang Xia, et al. Ferrocene particles incorporated into Zr-based metal-organic frameworks for selective phenol hydroxylation [J]. RSC Advances, 2017, 7: 38691-38698.

(28) Zhang Tianyong, Zhu Shaodi, Li Bin, Zhang Xia, et al. Synthesis of 4,4'-diamino-1,1'-dianthraquinone-3,3'-disulfonic acid in organic solvent systems [J]. CIESC Journal (化工学报), 2017, 68(1): 146-153.

(29)Zhang Guanghui, Zhang Tianyong, Li Bin, Zhang Xia, et al. Biomimetic synthesis of micro/nanostructured tubular TiO2 photocatalyst [J]. CrystEngComm, 2017, 19: 2312-2319.

(30)Zhang Guanghui, Zhang Tianyong, Li Bin, Zhang Xia, et al. Facile synthesis of TiO2 hierarchical tubes with enhanced photocatalytic activity [J]. Materials Research Bulletin, 2017, 94: 247-256.

(31) Zhang Xia, Zhang Tianyong, Wang Yanhong, et al. Electrochemical catalysis investigation into the dynamic coordination properties of a pyridine-substituted [2Fe2S] model complex [J]. International Journal of Hydrogen Energy, 2016, 41: 22991-22996.

(32) Jiang Shuang, Zhang Tianyong, Zhang Xia, et al. Synthesis, structural characterization, and chemical properties of pentacoordinate model complexes for the active site of [Fe]-hydrogenase [J]. RSC Advances, 2016, 6: 84139-84148.

(33) Wang Yanhong, Yang Yinwen, Zhang Tianyong, Zhang Xia, et al. A new nitrogen heterocyclic carbene containing diiron complex as bio-inspired catalyst for proton reduction and benzene hydroxylation [J]. Journal of Organometallic Chemistry, 2016, 825: 55-62.

(34) Zhang Guanghui, Zhang Tianyong, Li Bin, Zhang Xia, et al. Biomimetic synthesis of interlaced mesh structures TiO2 nanofibers with enhanced photocatalytic activity [J]. Journal of Alloys & Compounds, 2016, 668: 113-120.

(35) Gao Dameng, Zhang Xia, Kong Xia, Chen Yanli, Jiang Jianzhuang. (TFPP)Eu[Pc(OPh)8] Eu[Pc(OPh)8]/CuPc Two-Component Bilayer Heterojunction-Based Organic Transistors [J]. ACS Applied Materials & Interfaces, 2015, 7(4): 2486-2493.

(36) Gao Dameng, Zhang Xia, Luan Jiufeng, Chen Yanli. Design, synthesis, and aggregation behavior of sandwich mixed (phthalocyaninato)(porphyrinato) europium triple-deckers [J]. Inorganic Chemistry Communications, 2015, 54: 50-53.

(37) Kong Xia, Zhang Xia, Gao Dameng, et al. Air-stable ambipolar field-effect transistor based on a solution-processed octanaphthoxy-substituted tris (phthalocyaninato) europium semiconductor [J]. Chemical Science, 2015, 6(3): 1967-1972.

(38) Jiang Shuang, Zhang Tianyong, Zhang Xia, et al. Nitrogen heterocyclic carbene containing pentacoordinate iron dicarbonyl as a [Fe]- hydrogenase active site model [J]. Dalton Transactions, 2015, 44(38): 16708-16712.

(39) Zhang Xia, Gao Dameng, Gao Jian, et al. Morphology Controlled Nano-structures of an Octa(phenoxy)-substituted Phthalocyaninato Zinc complex [J]. RSC Advances, 2014, 4(28): 14807-14814.

(40) 陈艳丽, 张夏, 宋金刚. 一种构筑卟啉酞菁三明治型配合物特定形貌的方法 [P]. 中国专利: 201410015828.4, 2014.